name | ![]() | system | temperature |
![]() | 2.65 | trigonal | |
![]() | 2.53 | hexagonal | ![]() |
tridymite | 2.27 | hexagonal | ![]() |
cristobalite | 2.33 | cubic |
![]() |
coesite | 3.01 | ||
stishovite | 4.29 | octahedral |
The transition between and
-quartz is displacive, which means that no bonds are broken. It therefore transforms spontaneously to come to equilibrium with its environment. The transformation between
-quartz and tridymite is displacive, so bonds are actually broken and reformed. Both tridymite and cristobalite are metastable,
however, and will revert to
and
-quartz at surface conditions. Coesite is a stable polymorph found in the interior of the earth and at meteor crater. When a small amount of coesite is dissolved in HF, a small residue remains.
This residue contains SiO2 in the rutile structure, i.e., Si in octahedral coordination. Only 3 out of the 3500
surface minerals contain octahedral silicon, two out of three of which are only found in meteorites or impact craters. The
octahedral polymorph of silica is stishovite. A phase diagram of the phases of quartz can be found in Klein and Hurlbut
(1985).
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