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[Silica Polymorph]

   ℃〖化学〗2005-7-23 9:36

name system temperature
-quartz (low quartz) 2.65 trigonal  
-quartz (high quartz) 2.53 hexagonal C
tridymite 2.27 hexagonal C
cristobalite 2.33 cubic C
coesite 3.01    
stishovite 4.29 octahedral  

The transition between and -quartz is displacive, which means that no bonds are broken. It therefore transforms spontaneously to come to equilibrium with its environment. The transformation between -quartz and tridymite is displacive, so bonds are actually broken and reformed. Both tridymite and cristobalite are metastable, however, and will revert to and -quartz at surface conditions. Coesite is a stable polymorph found in the interior of the earth and at meteor crater. When a small amount of coesite is dissolved in HF, a small residue remains. This residue contains SiO2 in the rutile structure, i.e., Si in octahedral coordination. Only 3 out of the 3500 surface minerals contain octahedral silicon, two out of three of which are only found in meteorites or impact craters. The octahedral polymorph of silica is stishovite. A phase diagram of the phases of quartz can be found in Klein and Hurlbut (1985).

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