name | system | temperature | |
-quartz (low quartz) | 2.65 | trigonal | |
-quartz (high quartz) | 2.53 | hexagonal | C |
tridymite | 2.27 | hexagonal | C |
cristobalite | 2.33 | cubic | C |
coesite | 3.01 | ||
stishovite | 4.29 | octahedral |
The transition between and -quartz is displacive, which means that no bonds are broken. It therefore transforms spontaneously to come to equilibrium with its environment. The transformation between -quartz and tridymite is displacive, so bonds are actually broken and reformed. Both tridymite and cristobalite are metastable, however, and will revert to and -quartz at surface conditions. Coesite is a stable polymorph found in the interior of the earth and at meteor crater. When a small amount of coesite is dissolved in HF, a small residue remains. This residue contains SiO2 in the rutile structure, i.e., Si in octahedral coordination. Only 3 out of the 3500 surface minerals contain octahedral silicon, two out of three of which are only found in meteorites or impact craters. The octahedral polymorph of silica is stishovite. A phase diagram of the phases of quartz can be found in Klein and Hurlbut (1985).
回复Comments
{commenttime}{commentauthor}
{CommentUrl}
{commentcontent}