揭示大自然的规律

 

-=Chemistry=-

     >>  <<
我的日历
分类日志
友情链接
最新评论
搜索日志
访问计数
获取 RSS
我的 Blog:
iamet 最新的 20 条日志
[∑〖数学〗]
[Ω〖物理〗]
[¤〖天文〗]
[℃〖化学〗]
全站 Blog:
全站最新的 20 条日志

 

石榴石[Garnet]

   ℃〖化学〗2005-6-11 16:46
A class of mineral which has the general garnet structure X3Y2(ZO4)3, where Z = Si (for the silicate group), Y = Al, Cr, Mn+3, Fe+3, V+3, and X = Mn, Mg, Fe+2, and Ca.

Garnets may come directly from an igneous melt, and may be found in granites (Fe, Mn), and basalt flows (Mg, some Fe). They can also form from the gas phase at depth. A final mode of formation is in metamorphic rocks, where they may form in regional metamorphic environments composed of aluminum rich sediments (almandine), or in siliceous limestone where a magma and carbonate have come into contact (grossular).

Garnets can be made in the lab by powdering MgO, Al2O3, and SiO2. The powder is then placed inside gold or platinum tubes which are welded shut. (Gold and platinum are used since they do not melt and corrode at high temperatures and do not suffer oxidation). The capsule in then placed in a hydraulic press and brought to a pressure of 80-50,000 atm. An electrical current is run through the sample to attain temperatures of 1200 to 1400 . This simulates conditions 150 km below the surface.

name formula color (ions) locations
almandine Fe3Al2(SiO4)3 dark red (Fe+2), purple Colorado, Alaska, Nepal
andradite Ca3Fe2(SiO4)3 lime, yellow green (Cr+3) Italy
grossular Ca3Al2(SiO4)3 pink (Fe+2), colorless (pure),  
    pale green, orange-brown (Mn+2) Mexico, Tanzania, Canada
pyrope Mg3Al2(SiO4)3 colorless (Mg, Al), red Alps
spessartite Mn3Al2(SiO4)3 orange (Mn+2), dark red orange &;
uvarovite Ca3Cr2(SiO4)3 dark green  

Synthetic garnets include the following,

Abbr. Name Formula Use
GGG gadolinium gallium garnet Gd3Ga2(GaO4)3 Used in magnetic bubble memories
YAG yttrium aluminum garnet Y3Al2(AlO4)3 Synthetic gemstones

When doped with Nd+3, YAGs are useful as the lasing medium in lasers.

标签集:TAGS:
回复Comments()点击Count()

回复Comments

{commenttime}{commentauthor}

{CommentUrl}
{commentcontent}