Given a chemical equation of the form
then
In equilibrium,
For a chemical reaction
the law of mass action gives the rate as
where brackets denote concentrations and the reverse reaction is assumed to be negligible. Denote initial values with a 0 subscript and define
Since the amounts remaining of A and B after N molecules of C have been formed are and , we can rewrite (7) as
This is a nonlinear differential equation, but it can be separated and directly integrated
This integral is of the form
for q < 0, where , , and . The "discriminant" q is
Plugging the values for our problem into (13) gives
where C is a constant. Simplifying,
In order to find the value of C, we use the initial condition that , so plugging into (17) gives
Multiplying (17) through and exponentiating gives
Plugging (18) into (19) then gives
Solving for N,
gives the answer
Checking, we see that does indeed give 0, and gives .
(1)
then
(2)
(3)
In equilibrium,
(4)
(5)
For a chemical reaction
(6)
the law of mass action gives the rate as
(7)
where brackets denote concentrations and the reverse reaction is assumed to be negligible. Denote initial values with a 0 subscript and define
(8)
(9)
(10)
Since the amounts remaining of A and B after N molecules of C have been formed are and , we can rewrite (7) as
(11)
This is a nonlinear differential equation, but it can be separated and directly integrated
(12)
This integral is of the form
(13)
for q < 0, where , , and . The "discriminant" q is
(14)
(15)
Plugging the values for our problem into (13) gives
(16)
where C is a constant. Simplifying,
(17)
In order to find the value of C, we use the initial condition that , so plugging into (17) gives
(18)
Multiplying (17) through and exponentiating gives
(19)
Plugging (18) into (19) then gives
(20)
Solving for N,
(21)
gives the answer
(22)
Checking, we see that does indeed give 0, and gives .
回复Comments
{commenttime}{commentauthor}
{CommentUrl}
{commentcontent}