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键结强度[Bond Strengths]

   ℃〖化学〗2004-9-19 16:56
Strong (100-1000 kJ mol-1)
1. Macromolecular covalent bonds which exist between atoms in a crystal lattice (e.g., diamond, graphite, silica [SiO2], borazon []). Characteristics of macromolecular solids are a high melting point and electrical nonconductivity
2. Ionic bonds (e.g., NaCl, KCN). Characteristics of ionic solids are a high melting point and high electrical conductivity in the liquid phase.
Intermediate (10-50 kJ mol-1): Hydrogen bonds which form between a hydrogen atom and a more electronegative atom in the same or another polar molecule (e.g.,H2F2,, H3O+).
Weak (0-10 kJ mol-1):
1. Van der Waals forces (a.k.a., London dispersion forces) which result from instantaneous fluctuations in electron density distribution in nonpolar compounds (e.g., solid noble gases, CX4, CO2, C6H6).Characteristics include low melting point, softness, a tendency to sublime, poor heat conductivity, and nonconductivity of electricity.
2. Dipole attractions resulting from permanent dipole structures within a molecules (e.g., H2O, NH3). Characteristics of polar compounds are low to moderate melting point, variable hardness, and brittleness.
3. Metallic network forces characterized by a cationic network with an electron cloud distributed in the interstitial areas (e.g., Cu, Zn, Cr). Characteristics include luster, malleability, high heat and electrical conductivity

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